dc.contributor.author | Kadirsoy, Selcen | |
dc.contributor.author | Atar, Necip | |
dc.contributor.author | Yola, Mehmet Lütfi | |
dc.date.accessioned | 2020-05-24T15:31:47Z | |
dc.date.available | 2020-05-24T15:31:47Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Kadirsoy, S., Atar, N., Yola, M.L. (2020).
Molecularly imprinted QCM sensor based on delaminated MXene for chlorpyrifos detection and QCM
sensor validation. New Journal of Chemistry, 44(16), 6524-6532.
https://doi.org/10.1039/d0nj00951b | en_US |
dc.identifier.issn | 1144-0546 | |
dc.identifier.issn | 1369-9261 | |
dc.identifier.uri | https://doi.org/10.1039/d0nj00951b | |
dc.identifier.uri | https://hdl.handle.net/20.500.12508/1110 | |
dc.description | WOS: 000531201500044 | en_US |
dc.description.abstract | Chlorpyrifos (CHL) is one of the most frequently used broad-spectrum organophosphate insecticides. Especially, its incorrect and uncontrolled usage cause public concern about food and environment safety. In this report, a new molecularly imprinted quartz crystal microbalance (QCM) sensor on delaminated sulfur-doped MXene (d-S-Ti3C2TX MXene) was prepared for CHL. The structures of the bare MAX phase (Ti3AlC2), sulfur-doped MAX phase (S-Ti3AlC2), wrinkled sulfur-doped MXene (S-Ti3C2TX MXene) and d-S-Ti3C2SX MXene were highlighted by scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and X-ray diffraction (XRD). The CHL imprinted QCM sensor was prepared in the presence of MAGA and CHL in 2 : 1 molar ratio. From the analytical results 1.0 x 10(-12)-1.0 x 10(-10) M and 3.0 x 10(-13) M were found to be the linearity range and detection limit (LOD), respectively. Furthermore, the CHL imprinted QCM sensor was examined in terms of stability, repeatability, reproducibility and reusability. Finally, the imprinted sensor was applied to orange juice samples, and a high recovery was obtained. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation.isversionof | 10.1039/d0nj00951b | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject.classification | Chemistry | en_US |
dc.subject.classification | Multidisciplinary | en_US |
dc.subject.classification | Carbides | Titanium carbide | Metal carbides | en_US |
dc.subject.other | Glassy-carbon | en_US |
dc.subject.other | Electrochemical determination | en_US |
dc.subject.other | Voltammetric determination | en_US |
dc.subject.other | Quantum dots | en_US |
dc.subject.other | Nanosheets | en_US |
dc.subject.other | Surface | en_US |
dc.subject.other | Crystal atomic structure | en_US |
dc.subject.other | Cyclic voltammetry | en_US |
dc.subject.other | Electrochemical impedance spectroscopy | en_US |
dc.subject.other | Fourier transform infrared spectroscopy | en_US |
dc.subject.other | Fruit juices | en_US |
dc.subject.other | High resolution transmission electron microscopy | en_US |
dc.subject.other | Molar ratio | en_US |
dc.subject.other | Reusability | en_US |
dc.subject.other | Scanning electron microscopy | en_US |
dc.subject.other | Sulfur | en_US |
dc.subject.other | X ray photoelectron spectroscopy | en_US |
dc.subject.other | Analytical results | en_US |
dc.subject.other | Broad spectrum | en_US |
dc.subject.other | Detection limits | en_US |
dc.subject.other | Linearity range | en_US |
dc.subject.other | Molecularly imprinted | en_US |
dc.subject.other | Organophosphate insecticides | en_US |
dc.subject.other | Quartz crystal microbalance sensors | en_US |
dc.subject.other | Reproducibilities | en_US |
dc.subject.other | Quartz crystal microbalances | en_US |
dc.subject.other | Chlorpyrifos | en_US |
dc.subject.other | molecularly imprinted polymer | en_US |
dc.subject.other | Mxene | en_US |
dc.subject.other | Unclassified drug | en_US |
dc.subject.other | Atomic force microscopy | en_US |
dc.subject.other | Chemical structure | en_US |
dc.subject.other | Cyclic voltammetry | en_US |
dc.subject.other | Fourier transform infrared spectroscopy | en_US |
dc.subject.other | Impedance spectroscopy | en_US |
dc.subject.other | Limit of detection | en_US |
dc.subject.other | Priority journal | en_US |
dc.subject.other | Quartz crystal microbalance | en_US |
dc.subject.other | Scanning electron microscopy | en_US |
dc.subject.other | Transmission electron microscopy | en_US |
dc.subject.other | Validation process | en_US |
dc.subject.other | X ray diffraction | en_US |
dc.subject.other | X ray photoemission spectroscopy | en_US |
dc.title | Molecularly imprinted QCM sensor based on delaminated MXene for chlorpyrifos detection and QCM sensor validation | en_US |
dc.type | article | en_US |
dc.relation.journal | New Journal of Chemistry | en_US |
dc.contributor.department | Mühendislik ve Doğa Bilimleri Fakültesi -- Biyomedikal Mühendisliği Bölümü | en_US |
dc.identifier.volume | 44 | en_US |
dc.identifier.issue | 16 | en_US |
dc.identifier.startpage | 6524 | en_US |
dc.identifier.endpage | 6532 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.contributor.isteauthor | Kadirsoy, Selcen | en_US |
dc.contributor.isteauthor | Yola, Mehmet Lütfi | en_US |
dc.relation.index | Web of Science - Scopus | en_US |
dc.relation.index | Web of Science Core Collection - Science Citation Index Expanded | en_US |